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2024-01-12 11:16:03 | onclick: | Implementing molecular "surgery", carbon materials family "added new Ding

Xu Wei's team, a professor at Tongji University's School of Materials Science and Engineering, synthesized a ring-shaped pure carbon molecule consisting of 10 or 14 carbon atoms for the first time by "anesthesia" and "surgery".
For the first time, two novel carbon molecular materials (carbon allografts), aromatic cyclic carbon C10 and C14, have been synthesized with precision and have been characterized by their chemical structures.
Surface synthesis strategies and chemical structure characterization of cyclic carbon C10 and C14.Tongji University of Technology
Carbon is a common nonmetallic element, and carbon materials have many forms in nature, and their specific external appearance depends on the number of atoms bonded to each carbon atom around it.When each carbon atom binds to the surrounding four atoms, it forms a hard and transparent material naturally occurring in nature—diamonds; when it binds to the surrounding three atoms, it forms a qualitative soft black graphite.
When each carbon atom binds to only two surrounding atoms, it forms a ring-shaped pure carbon molecule (cyclic carbon, Cn).Because this type of carbon structure is highly reactive, highly unstable, does not occur naturally in nature, and synthetic is extremely challenging.
In addition, in cyclic carbon, the way in which each carbon atom and the surrounding two atoms bond, i.e., cumulative olefin type with equal bond length (continuous double bond) or polyacetylene type (single bond and triple bond alternation).Therefore, the most fundamental problems of their puzzling structure and stability have attracted great interest from experimentalists and theorists.Many teams have tried unsuccessfully to synthesize cyclic carbon, and some gas-phase experiments have shown signs of cyclic carbon, but it is difficult to separate and refine and further characterize their structure.
Until 2019, IBM Labs and Oxford University research teams prepared a single cyclic carbon C18, the first experimental verification of C18 as a single- and triple-bond alternating polyacetylene structure.However, cyclic carbon is a large family, and for smaller cyclic carbon, their synthesis becomes more challenging due to their small size.
In this study, the team innovatively designed two precursor molecules, all-halogenated naphthalene and anthracene.The two molecules were placed on the operating table (sodium chloride film) and "anesthetized" (liquid helium 4.7 K frozen), and then "surgical" (atomic manipulation) to induce complete dehalogenation.Chemical bond resolution atomic force microscopy shows that C10 and C14 have accumulated olefin structures, unlike the previous polyacetylene structures of C18.
The team further found that the two carbon material family members do not have completely identical properties, C10 does not have any bond length alternation, and C14 as a cumulative olefin type C10 to polyacetylene type C18.
"This research work has greatly promoted the development of the cyclic carbon field, and the proposed surface synthesis strategy is expected to become a universal method for the synthesis of cyclic carbon series.""At the same time, the synthesized cyclic carbon is expected to develop into a new type of semiconductor material and have broad application prospects in molecular electronic devices."

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